Two New Diterpenoids from Isodon rubescens

In order to further study on minor diterpenoid constituents of lsodon rubescens, wereinvestigated this species, which was collected in Taibai mountain, Shaanxi Province.TWo new diterpenoids, taibairubescensins A (l) and B (2), were isolated. In this paper,we present the structure elucidation of these two new diterpenoids.Taibairubescensin A (l ), C,.H,#O, (FABMS m/z 435[M 11 ), an amorphous powder,showed UV and iR absorption bands for the existence of hydroxyl, acetoxyl and a fivemembe…     

Two New Sterols from Amoora yunnanensis

ThegenusAmooracomprisingabout25-3ospeciesisdistributedinIndiaandtheMalayPeninsula.SixspeciesaredistributedinYunnanprovince.Amoorayunnanensis(H.L.Li)C.YWu,ismainlydistributedintheSouthofYunnanl.AccordingtoPenningtonandStyles',Amooracannotbeconsideredasavalidgenus.UptonoWchemicalconstituentsforthisgenushavenotbeenreportedyet.lnourchemicalstudyonAmoorayunnanensis,tetTanortfiterPenoidsorprotolimonoidsthatwereconsideredaschemotaxonomicmarkersofthefamilyMeliaceae,werenotisolated.lnthispaper…     

1,2-二苄硫基乙烯撑二硫金属配合物的合成

合成了11种未见文献报道的苄硫基乙烯撑二硫金属配合物,研究了它们的元素分析、IR和US/vis光谱,讨论了形成不同产物的原因.对钾取代苄基提出了一个合理机理.     

The mechanism of asymmetric reduction catalyzed by a C2 symmetric bis-amino alcohol catalyst

By means of¹H,¹³C,¹¹B NMR, polar transfer DEPT135, DEPT90 and 2D NMR experiments, IR, etc, the structure of the diaminodihydroxyl ligand and its derivatives used in the asym-metric reduction of prochiral ketones were detected. The catalysts derived from the ligand and borane formedin situ were also studied and the structure transformations in solution were monitored. The structure of the catalyst was proved to be a new type of dual-centered catalyst — bisoxazaborolidine.     

密频系统振动控制的状态估计

首先在研究了重频系统中状态可观察的必要条件基础上,给出了设计重频系统状态估计器的方法,使得状态估计的误差能以事先指定的速率衰减。随后给出两种方法将上述重频系统的估计器用到密频系统上去：一种是直接用重频系统估计器来估计密频系统状态,另一种是用按重频系统设计得到的估计矩阵构造密频系统的观察器,并分析由此引起的误差。分析表明,第一种方法简单易行,并且在频率分散度比较小时可以得到理想的结果;第二方法的精度较高,其误差与状态变量本身无直接关系。数值例子表明,用提出的状态估计器,并按相应的状态控制器,可以使密频系统的振动按事先给定的衰减程度趋向于零。     

摩托车正时链和传动链磨损特性的研究

研究油润滑条件下摩托车发动机正时链的磨损特性,发现疲劳磨损,裂纹的形成和扩展是影响疲劳寿命的主要因素;定期刷油或滴油润滑条件下,摩托车传动链的磨损机制是磨粒磨损,并伴有疲劳磨损,销轴和套筒零件的渗层及心部组织等是影响链条磨损特性的重要因素,因为中碳调质钢经碳氮共渗后可获得弥散分布的颗粒状碳化物的表层组织及回火屈氏体的心部组织,从而显示出表层耐磨、心部强韧性好及抗塑变能力高的综合机械性能。     

一类抛物型方程的粘性解

讨论一类退化、奇异抛物型方程的初边值问题. 通过构造上下解 ,利用粘性解的比较原理和 Perron方法 ,证明了这类问题粘性解的存在性和唯一性.     

二茂铁甲酰基1,1'-二烷基二茂铁的合成与性质

在研制丁羟固体推进剂的高效不迁移燃速催化剂中 ,我们设计的目标物的结构为ＦｃＣＨ (ＯＨ)Ｆｃ′Ｒ2 (Ｆｃ =Ｃ5Ｈ5ＦｅＣ5Ｈ4 ,Ｆｃ′=Ｃ5Ｈ4 ＦｅＣ5Ｈ3,Ｒ为烷基 ) .该类化合物的特点是两个二茂铁核连在同一碳上 ,且含有羟基官能团 ,它们似应具有高效和不迁移的燃速催化性能[1].此类化合物的合成是由二茂铁甲酰基 1,1′ 二烷基二茂铁化合物的羰基还原为羟基实现的 .为此 ,我们较为详细地研究了 5种二烷基二茂铁在三氯化铝催化下的二茂铁甲酰化反应 .此项工作未见报道 .二烷基二茂铁的茂环有α(与烷基相邻 )和 β(与烷基相间 )两种Ｈ原…     

Preparation and Characterization of Aluminum Alkoxides and their Application to Ring‐Opening Polymerization of ϵ‐Caprolactones

The reaction of 2‐methoxybenzyl alcohol with one molar equiv of R₂AIX in diethyl ether at 0°C gives [(2‐MeOC₆H₄CH₂‐μ‐O)AlRX]₂ ( 1 : R = Et, X = Cl, 2 : R = X = Et). In addition, 2,4‐di‐tert‐butylphenol reacts with ⁱBu₃Al affording a four‐coordinated aluminum compound [(μ‐2,4‐^tBu₂‐C₆H₄O)Al(ⁱBu)₂]₂ ( 4 ). Single crystal X‐ray structure analysis of 4 shows a C_2h‐symmetry with a planar Al₂O₂ core. Ring‐opening polymerization (ROP) of caprolactones initiated by 1, 4 and [(μ‐OCH₂C₆H₄OMe)Al(ⁱBu)₂]₂ ( 3 ) is performed and polyesters with narrow molecular weight distributions were obtained from the “living” ROP of caprolactones. ¹H NMR spectroscopic studies of PCL reveal that the initiator of 1 and 3 is through the Al‐OAr function, but the initiator of 4 is through the Al‐ ⁱBu group.     

Extraction of Uranium(VI) by N-Octanoylpiperidine in Toluene

The extraction of uranium(VI) from nitric acid by N-octanoylpiperidine (OPPD) in toluene has been investigated at varying concentrations of nitric acid, extractant, salting-out agent LiNO₃ and at different temperatures. The mechanism of extraction is discussed in the light of the results obtained. The extracted species have also been investigated using FT-IR spectrometry. The related thermodynamic functions were calculated.